具体描述
Assuming no previous knowledge of polymers, this book provides a general introduction to the physics of solid polymers. Covering a wide range of topics within the field of polymer physics, the book begins with a brief history of the development of synthetic polymers and an overview of the methods of polymerization and processing. In the following chapter, David Bower describes important experimental techniques used in the study of polymers. The main part of the book, however, is devoted to the structure and properties of solid polymers, including blends, copolymers and liquid crystal polymers.
Materials Science and Engineering: Fundamentals and Applications A Comprehensive Textbook for Undergraduate and Graduate Students This textbook provides a rigorous and comprehensive exploration of the fundamental principles governing the structure, properties, processing, and performance of materials, catering to advanced undergraduate and introductory graduate students in materials science, engineering, chemistry, and physics. It meticulously bridges the gap between microscopic atomic/molecular structure and macroscopic engineering behavior, offering a holistic perspective essential for modern materials innovation. --- Part I: Atomic and Microstructural Foundations This section lays the groundwork by examining the fundamental building blocks of matter and how their arrangement dictates macroscopic properties. Chapter 1: Introduction to Materials Science and Engineering Defining materials science and engineering: Scope, historical context, and the materials selection paradigm. The essential triangle: Structure, Properties, Processing, and Performance. Classification of materials: Metals, Ceramics, Polymers, and Composites—a comparative overview. The role of sustainability and lifecycle analysis in modern materials design. Chapter 2: Atomic Structure and Bonding Quantum mechanical basis of atomic structure: Electron configuration and orbital theory. The periodic table: Trends in electronegativity, atomic radii, and ionization energy. Primary bonding mechanisms: Ionic, covalent, and metallic bonding—energy considerations and characteristic strengths. Secondary bonding forces: Van der Waals interactions (London dispersion, dipole-dipole) and hydrogen bonding; their significance in intermolecular cohesion. Introduction to molecular orbital theory for understanding complex structures. Chapter 3: Crystalline Structure and Imperfections Crystallography fundamentals: Lattices, unit cells, Miller indices, and crystallographic directions/planes. Common metallic crystal structures: Face-Centered Cubic (FCC), Body-Centered Cubic (BCC), and Hexagonal Close-Packed (HCP). Calculation of packing factor and theoretical density. Ceramic crystal structures: Concepts of stoichiometry, charge neutrality, and coordination number (e.g., CsCl, NaCl, Zinc Blende structures). Radius ratio rules. Defects in solids: Point defects (vacancies, interstitials, substitutional atoms) and their thermodynamic equilibrium concentration. Line defects (Dislocations): Burgers vector, edge and screw dislocations, and their role in plastic deformation. Planar defects: Grain boundaries (coincidence site lattice theory), twin boundaries, and stacking faults. Chapter 4: Thermal Properties of Solids Lattice vibrations and phonons: The quantization of vibrational energy. Heat capacity of solids: Classical (Dulong-Petit law) versus quantum mechanical treatment (Einstein and Debye models). Thermal conductivity: Mechanisms of heat transfer in crystalline versus amorphous solids. The role of defects in scattering phonons. The concept of thermal diffusivity and its measurement. Thermal expansion: Linear and volumetric coefficients; implications for engineering design (thermal mismatch). --- Part II: Phase Transformations and Mechanical Behavior This section delves into how temperature and mechanical stress influence the microstructure and resulting mechanical performance of materials. Chapter 5: Thermodynamics and Phase Equilibria Introduction to the thermodynamics of materials: Gibbs Free Energy ($G$) as the criterion for equilibrium. Phase diagrams: Interpretation of unary and binary phase diagrams (e.g., the Lever Rule, interpretation of eutectic and eutectoid reactions). Solid solutions: Hume-Rothery rules for substitutional and interstitial solubility. The Iron-Carbon System: Detailed analysis of the Fe-Fe$_3$C diagram, including microconstituents like Ferrite, Austenite, Cementite, Pearlite, and Bainite. Chapter 6: Kinetic Processes and Diffusion Mass transport in solids: Mechanisms of diffusion (substitutional and interstitial). Fick’s Laws of Diffusion: Steady-state and non-steady-state diffusion equations. Factors influencing diffusion rates: Temperature dependence (Arrhenius relationship), diffusion coefficients, and material microstructure. Phase transformations kinetics: Nucleation theory (homogeneous vs. heterogeneous) and growth mechanisms. The concept of an activation energy barrier for transformation. Chapter 7: Mechanical Properties: Elasticity and Plasticity Stress and Strain: Uniaxial loading, Hooke's Law, elastic moduli (Young's Modulus, Shear Modulus, Bulk Modulus). Poisson's Ratio. Viscoelasticity overview: Introduction to the concepts of creep and stress relaxation, necessary for analyzing non-metallic materials. Plastic Deformation in Metals: The critical role of dislocation motion. Slip systems in FCC, BCC, and HCP materials. Critical Resolved Shear Stress (CRSS). Work Hardening (Strain Hardening): Mechanisms and quantification. Strengthening Mechanisms: Grain size reduction (Hall-Petch relationship), solid solution strengthening, precipitation hardening (age hardening), and dislocation entanglement. Chapter 8: Fracture and Fatigue Modes of Fracture: Ductile vs. Brittle fracture; macroscopic characteristics (microvoid coalescence vs. cleavage). Griffith Theory of Brittle Fracture: Stress intensity factors ($K_I, K_{II}, K_{III}$) and the critical stress intensity factor ($K_{IC}$, Fracture Toughness). Crack Propagation: Stable vs. unstable fracture. Fatigue failure: Stress-life (S-N curves), mechanisms of fatigue crack initiation and propagation, and the concept of endurance limit. Creep and High-Temperature Failure: Mechanisms of creep (Nabarro-Herring, Coble creep) and stress rupture. --- Part III: Processing, Structure Control, and Applications The final section links the fundamental physics and mechanical behavior to practical manufacturing routes and the specific properties of key material classes. Chapter 9: Processing of Metals and Ceramics Metal processing: Casting (solidification theory, gating, risering), forming (rolling, forging, extrusion), and powder metallurgy. Ceramic processing: Powder preparation, forming techniques (pressing, slip casting), and high-temperature sintering (densification mechanisms, liquid-phase sintering). Heat treatment of alloys: Annealing, quenching, tempering, and precipitation hardening sequences for microstructural control. Chapter 10: Electrical and Magnetic Properties Electrical Conductivity in Solids: Classical theory (Drude model) and quantum mechanical band theory (insulators, semiconductors, conductors). Effective mass concept. Semiconductor Physics: Intrinsic vs. extrinsic semiconductors, doping, the Fermi level, and the operation of $p-n$ junctions (brief overview). Dielectric Materials: Polarization mechanisms (electronic, ionic, orientational) and permittivity. Breakdown strength. Magnetic Properties: Diamagnetism, paramagnetism, ferromagnetism, and antiferromagnetism. Hysteresis loops and magnetic domains. Soft vs. hard magnetic materials. Chapter 11: Materials for Energy and Environment Corrosion Science: Thermodynamics and kinetics of electrochemical corrosion. Passivity layers. Methods for corrosion prevention (coatings, cathodic protection). Introduction to Photovoltaics: Semiconductor junctions and light absorption. Catalysis and Surface Phenomena: Importance of surface energy and surface area in heterogeneous catalysis. Chapter 12: Engineering Composites and Advanced Materials Composite fundamentals: Classification (particle-reinforced, fiber-reinforced, structural). Isostrain and isostress assumptions for longitudinal and transverse loading. Fiber reinforcement: Role of matrix and interface in load transfer. Continuous vs. discontinuous fibers. Interfacial science: The critical role of the fiber-matrix interface in composite performance and failure mechanisms. --- This textbook emphasizes problem-solving derived directly from physical principles, utilizing extensive worked examples and end-of-chapter problems to solidify comprehension.
