Spin Spirals and Charge Textures in Transition-Metal-Oxide Heterostructures pdf epub mobi txt 电子书 下载 2025

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Nominated as an outstanding Ph.D. thesis by the Max Planck Institute for Solid-State Research, Stuttgart, Germany

Provides a clear summary of the properties of nickelates and cuprates, particularly useful for readers new to the field of transition-metal-oxides

Includes a detailed outline of experimental and theoretical principles of x-ray diffraction

Descriptive pictorials facilitate an intuitive understanding of the results

This thesis presents the results of resonant and non-resonant x-ray scattering experiments demonstrating the control of collective ordering phenomena in epitaxial nickel-oxide and copper-oxide based superlattices. Three outstanding results are reported: (1) LaNiO3-LaAlO3 superlattices with fewer than three consecutive NiO2 layers exhibit a novel spiral spin density wave, whereas superlattices with thicker nickel-oxide layer stacks remain paramagnetic. The magnetic transition is thus determined by the dimensionality of the electron system. The polarization plane of the spin density wave can be tuned by epitaxial strain and spatial confinement of the conduction electrons. (2) Further experiments on the same system revealed an unusual structural phase transition controlled by the overall thickness of the superlattices. The transition between uniform and twin-domain states is confined to the nickelate layers and leaves the aluminate layers unaffected. (3) Superlattices based on the high-temperature superconductor YBa2Cu3O7 exhibit an incommensurate charge density wave order that is stabilized by heterointerfaces. These results suggest that interfaces can serve as a powerful tool to manipulate the interplay between spin order, charge order, and superconductivity in cuprates and other transition metal oxides.

Frano, Alex,德国马普研究所博士毕业。目前在劳伦斯伯克利国家实验室从事研究。

1 The System: Transition Metal Oxides
and Their Heterostructures ............................. 1
1.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2 Transition Metal Oxides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.2.1 Crystal Structure . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.2.2 Electronic Structure. . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.3 TMO Heterostructures . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2 The Technique: Resonant X-ray Scattering . . . . . . . . . . . . . . . . . . 19
2.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
2.2 X-ray Sources: Synchrotron Radiation . . . . . . . . . . . . . . . . . . . 20
2.3 Resonant Scattering . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
2.3.1 Basic Principles of X-ray Physics . . . . . . . . . . . . . . . . . 23
2.3.2 The Interaction of Light with Matter . . . . . . . . . . . . . . . 26
2.3.3 XAS Cross Section . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
2.3.4 Magnetic Scattering: Symmetry Considerations . . . . . . . 33
2.3.5 Experimental Access to Reciprocal Space . . . . . . . . . . . 39
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
3 The Nickelates: A Spin Density Wave . . . . . . . . . . . . . . . . . . . . . . 47
3.1 Properties of Bulk RNO . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
3.1.1 Electronic Configuration and the Torrance
Phase Diagram . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
3.1.2 The MIT: Charge Disproportionation. . . . . . . . . . . . . . . 49
3.1.3 AFM Order: Noncollinear Spiral. . . . . . . . . . . . . . . . . . 51
3.1.4 A SDW-Nested Fermi Surface . . . . . . . . . . . . . . . . . . . 54
3.2 Properties of LNO SLs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
3.2.1 Reconstructing LNO . . . . . . . . . . . . . . . . . . . . . . . . . . 55
3.3 Experimental Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 60
3.3.1 Structural Details of LNO SLs . . . . . . . . . . . . . . . . . . . 60
3.3.2 Magnetic Order in LNO. . . . . . . . . . . . . . . . . . . . . . . . 68
3.3.3 Magnetic Structure of RNO Films. . . . . . . . . . . . . . . . . 75
3.3.4 Models: Collinear Versus Noncollinear Spins . . . . . . . . . 77
3.4 Discussion and Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . 81
3.4.1 Orbital Polarization Altering the Magnetic Structure . . . . 81
3.4.2 Remanent Conductance in the SDW State
and the Question of Concomitant CO . . . . . . . . . . . . . . 83
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
4 The Cuprates: A Charge Density Wave . . . . . . . . . . . . . . . . . . . . 91
4.1 Properties of Bulk YBCO. . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
4.2 CDW Order in YBCO Single Crystals . . . . . . . . . . . . . . . . . . . 106
4.2.1 Discussion and Conclusions . . . . . . . . . . . . . . . . . . . . . 116
4.3 CDW Order in YBCO-LCMO Heterostructures. . . . . . . . . . . . . 119
4.3.1 Properties of Heterostructured YBCO . . . . . . . . . . . . . . 119
4.3.2 Experimental Results. . . . . . . . . . . . . . . . . . . . . . . . . . 120
4.3.3 Discussion and Conclusions . . . . . . . . . . . . . . . . . . . . . 130
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
Appendix A: The Kramers-Kronig Relations . . . . . . . . . . . . . . . . . . . 139
Appendix B: Quantization of the Light Field . . . . . . . . . . . . . . . . . . . 141
Appendix C: Fermi’s Golden Rule . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Appendix D: Mathematica Script to Analyze
Azimuthal Dependencies . . . . . . . . . . . . . . . . . . . . . . . . 147
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