Radical Reactions in Organic Synthesis (Oxford Chemistry Masters)

Radical Reactions in Organic Synthesis (Oxford Chemistry Masters) pdf epub mobi txt 电子书 下载 2025

出版者:Oxford University Press, USA
作者:Samir Z. Zard
出品人:
页数:272
译者:
出版时间:2004-01-01
价格:USD 76.45
装帧:Paperback
isbn号码:9780198502401
丛书系列:
图书标签:
  • 有机合成
  • 自由基反应
  • 氧化化学
  • 化学反应
  • 有机化学
  • 合成方法
  • 硕士教材
  • 牛津大学出版社
  • 化学研究
  • 反应机理
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具体描述

Zard provides a description of radical reactions and their applications in organic synthesis. He illustrates that armed with an elementary knowledge of kinetics and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems. The book begins with a brief historical account and presentation of the basics. It then blends the discussion of the properties of radical processes with the now familiar chemistry of stannanes. Radicals being the same entities, whichever method is used to generate them, a study of the various processes for the creation and capture of radicals constitutes the remainder of the book. Silicon and mercury based techniques as well as the Barton and related decarboxylation procedures are discussed in detail, followed by the Kharasch type atom and group transfer reactions. The increasingly important persistent radical effect, also known as the Fischer-Ingold effect, is examined in the context of non-chain reactions. Both the Kharasch based methods and the persistent radical effect have recently been applied in the emerging field of controlled radical polymerisations. Finally, the vast domain of redox processes is presented in a unified manner with the aim of providing a simple rationale for the multitude of possible transformation. The book concludes with a brief overview and some general practical hints for conducting radical reactions. More than 700 references provide access to the primary literature.

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